Sterling is just fine for chain, but as you alluded to in your post that AR is probably too big - I make roundmaille with 16awg 11/64 - your 4.5mm ID is larger than 11/64, and you're a whole wire gauge smaller. You might have some problems, especially if he is going to wear it 24/7. Now, the good thing about wearing it 24/7 is all that wear and banging around will harden the wire pretty quickly.
If nothing else, I would solder the rings b/w the chain and clasp or double/triple those rings if you don't solder and check for loose or rings opening often - maybe once a week.