I have done a tiny bit of coloring of copper using heat - get a reddish color. I found this site that tells how to get some different colored patinas on copper & other metals using chemicals. This may help someone.
http://www.sciencecompany.com/patinas/index.htm
Also found this at www.artsandcraftsmetalwork.com - using heat.
There is also the very interesting method of coloring copper by heat. In this method no chemicals of any kind are used; all that is necessary is that the metal shall be perfectly clean and that it be slowly passed to and fro thru a blue gas flame, such as is obtained from a Bunsen burner or any ordinary gas stove. It is also possible to get results from other heating methods such as a clear hard coal fire, but the trouble with such methods is that the article is very liable to get smoked.
The colors obtained by the heat method come in this order if it is done slowly : First, orange red; Second, bluish purple; Third, brassy color; Forth, dark red; Fifth, deep purple; Sixth, iridescent; Seventh, chestnut color.The first two colors partially come off when the lacquer or wax is applied. All the others are permanent if they are lacquered or waxed. The lacquer is applied as soon as the article is cold, the wax while it is still warm. Care must be taken when obtaining the chestnut color not to pass it into the flame any more when the chestrlut color begins to come, because if the chestnut color is carried too far the color will flake off and the entire process of cleaning and coloring will have to be repeated.
I think this is what you are talking about.
Debbie Moyer
DeMoy Jewelry Designs